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Chemical News

Condividi contenuti RSC - Green Chem. latest articles
RSC - Green Chem. latest articles
Aggiornato: 13 ore 44 min fa

Interfacial engineering of S-scheme ZnIn2S4/CoPPc for photoinduced H2 production coupled with benzyl alcohol valorization

12 novembre, 2025 - 03:37

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03212A, PaperYing Jiang, Dongfang Hou, Siyue Li, Sinan Xiao, Jiashuo Liu, Fenglan Lu, Xiu-Qing Qiao, Bojing Sun, Dong-Sheng Li
This study shows that the synergistic effect of a strong interface electric field, single-atom active sites, and photothermal effects of VDZIS/CoPPc can simultaneously improve photocatalytic hydrogen energy and high-value chemical production.
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Cascade synthesis of diarylamines catalyzed by oxygen-rich and porous carbon

2 novembre, 2025 - 18:05
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC05166E, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Juho Pekka Helaja, Anna Lenarda, Itisha Jain, Aleksi Kaleva, Valtteri Oksanen, Sami Heikkinen, R. T. Koivula, Tom Wirtanen, Michele Melchionna, Tao Hu
Activated carbon derived porous materials, effectively enriched with OH and C=O groups, were found to mediate, in a cascade manner, the condensation between anilines and 3-hexenones or β-tetralones, followed by...
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Solvent-Induced Microstructure Disruption and Catalytic Activation Synergy Toward Mild and Rapid Degradation of Epoxy Thermosets

2 novembre, 2025 - 18:05
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04437E, PaperKe Li, Xu Zhao, Dongchu Liu, Weifeng Jia, Qiang Peng
Epoxy thermosets' superior properties enable widespread applications, yet simultaneously impose persistent environmental burdens. Current recycling approaches remain hindered by insufficient understanding of degradation mechanisms and inadequate process control, resulting in...
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Green polymerisation of renewable lignin-derived vinyl ketone monomer to form UV-degradable polymers

2 novembre, 2025 - 18:05
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04711K, PaperThomas Joseph Neal, Arturo Josue Ledezma Fierro, Fanny Coumes, Giovanni Poli, Alexandre Pradal, Jutta Rieger
We report the synthesis of a novel aromatic vinyl ketone monomer (BioPVK) from an abundant product of lignin depolymerisation, syringaldehyde. We demonstrate that BioPVK can be homopolymerised and copolymerised with...
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Enhanced production of dimethyl carbonate from the alternating polarity electrolysis of methanol and carbon dioxide

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02358K, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Momoko Ishii, Maria M. Paulsen, Remi A. Mellinghoff, Heather O. LeClerc, Ho Yin Tse, Hanno C. Erythropel, Julie B. Zimmerman, Paul T. Anastas, Darren S. Lee
Alternating polarity enhanced redox-neutral electrochemical formation of dimethyl carbonate (DMC) from CO2 and methanol. Alternating the polarity was found to be necessary for efficient reoxidation of Pd0 → Pd2+ thus enabling higher yields of DMC.
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Intrinsic dual active sites synchronously regulate the solvation structure and interface to boost a highly stable Zn anode

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02878G, PaperHui Peng, Kaifa Dong, Xin Wang, Yaping Jing, Pengyun Xie, Xuan Xie, Zhe Zhang, Guofu Ma
Green CPL co-solvents work by restructuring the Zn2+ solvation structure and the electrode/electrolyte interface Helmholtz layer, building a dynamic SEI, and favoring Zn(002)-oriented nucleation, which enables efficient Zn2+ energy storage systems.
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Resonant acoustic mixing enables solvent-less amide coupling in solid-phase peptide synthesis

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04067A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Alice Nanni, Panayiotis Bilalis, Magnus Rueping
Resonant acoustic mixing (RAM) as a mechanochemical alternative to traditional SPPS processes enables efficient and scalable peptide coupling without added solvent, supporting sustainable synthesis of bioactive peptides.
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Precipitation-first synthesis and deep profiling of a 1200-member acrylamide library for covalent drug discovery

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04440E, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Pravin Patil, Emis Ingenito, Riccardo Fusco, Imma Capriello, Zhirui Guan, Anuja Bhalkikar, John Gibbons, Tomas Korba, Stanislav Bashkyrtsev, Oleh Tkachenko, Alexander Dömling
We developed an efficient Ugi-based route to 1200 acrylamides, delivering millimolar quantities of pure precipitated products. Library quality was verified by 1H NMR, UPLC-UV-MS, and AEMS, yielding a sustainable drug-discovery-ready set.
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A melamine foam-scaffolded LDHs@PVA gel electrolyte with high ionic conductivity and water retention capability for flexible zinc–air batteries

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04158A, PaperYonghang Zeng, Yanhong Gong, Wenhao Wang, Xinglong Song, Dongbin Xiong, Yue Du, Lina Zhou, Yi Cao, Faqi Zhan, Yisi Liu
Melamine foam as a 3D scaffold for in situ growth of vertically aligned CoNi-LDH arrays to prepare MF-LDHs@PVA GPE with high ionic conductivity and water retention capability for flexible zinc-air batteries.
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Synergistic enhancement of evaporation-driven power generation via thermoelectric coupling at elevated temperatures

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03587B, CommunicationXin Zhou, Changhao Li, Jianfeng Lin, Guang Yang, Zipei Zhang, Zhangfeng Wu, Mi Lu, Jianping Lin
We overcame low power limitations using a novel hybrid evaporative–thermoelectric generator. This sustainable synergy yielded 11.37 W m−2 (31.45% increase) at 100 °C with a p-Bi2Te3 device.
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Recent advancements in microbial carbon dioxide fixation: metabolic engineering strategies

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03349G, Tutorial ReviewZeeshan Mustafa, Naeem Auroona, Arslan Sarwar, Eun Yeol Lee
Engineered microbes utilize natural and synthetic pathways to capture industrial CO2 emissions. The assimilated carbon is transformed into bioplastics and biofuels, contributing to a cleaner and sustainable environment.
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Aligning platinum recycling with hydrogen economy growth: a comparative LCA of hydrometallurgical and pyrometallurgical methods

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02447A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jessica Lord, Robert White, Richard Murphy, Jhuma Sadhukhan
Combination of LCA and MFA to project critical implementation timing for sustainable platinum recycling from proton exchange membrane fuel cells.
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How to make furfural and HMF production greener? Lessons from life cycle assessments

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03729H, Critical ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ouwen He, Bailey A. Smith, Pascale Champange, Philip G. Jessop, Hongbing Yu
The environmental impacts of synthesizing HMF and furfural from biomass can best be reduced by process modifications guided by the results of life cycle assessments.
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Rapid recovery of precious metals via photocatalytic-assisted solvometallurgy using an ethylene glycol-based solvent

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04641F, PaperAnting Ding, Qibin Yan, Chenchen Zhu, Ming Li, Chuanying Liu, Chengliang Xiao
A green and sustainable method using EG-AlCl3·6H2O solvent for recycling of precious metals.
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Graphitic carbon nitride/nickel dual catalysis for decarboxylative synthesis of unsymmetrical ketones from keto acids

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03641K, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Michael T. Findlay, Florian Lukas, Francesca Rizzo, Junsong Liu, Benjamin Martin, Simon Allmendinger, Markus Furegati, Pablo Gabriel, Timothy Noël
Sustainable dual-catalysis with graphitic carbon nitride (gCN) and nickel for ketone and amide synthesis from α-keto and oxamic acids.
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Synergistic visible-light/Brønsted-acid promoted deconstructive aminoalkylation of spiro dihydroquinazolinones: modular synthesis of α-functionalized unnatural amino acids

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04059K, CommunicationWen-Peng Yang, Hong-Jie Miao, Jia-Yi Li, Xin-Hua Duan, Li-Na Guo
Synergistic visible-light/Brønsted-acid promoted deconstructive aminoalkylation of spiro-dihydroquinazolinones with aromatic amines and ethyl glyoxylate is presented.
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Mechanism-infused machine learning for scattered metal recovery: SHAP decodes multiscale physicochemical drivers in refractory matrices

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04492H, PaperJiayu Zhang, Ji Zhang, Ping Zhu, Zhenming Xu, Lingen Zhang
This research optimized the recovery process through machine learning and SHAP analysis, utilizing fly ash to replace toxic chlorinating agents, thereby achieving efficient and environmentally sound recovery of multiple scattered metals.
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Perovskite-triggered dual exsolution of oxygen-deficient CeO2 matrix and NiFe nanoalloys for enhanced CO2 electrolysis

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04390E, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Biao Ouyang, Ming Yang, Lin-Bo Liu, Shuo Liu, Yan Li, Xian-Zhu Fu, Yifei Sun, Subiao Liu, Jing-Li Luo
Sr1.95Ce0.05Fe1.3Ni0.2Mo0.5O6−δ with optimal Ce doping allowed in situ co-exsolving CeO2 phase and NiFe nanoalloys on the surface, which achieved a high current density of 1.57 A cm−2 at 1.5 V and 850 °C with a CO faradaic efficiency of over 96%.
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Oxygen vacancy-hydroxyl frustrated Lewis pairs enabling CO2 cycloaddition for halogen-free synthesis of cyclic carbonates

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04831A, PaperChengguang Yue, Jiaxin Li, Mei-Yan Wang, Zhiyi Yang, Tiantian Xiao, Ji Qi, Shouying Huang, Yue Wang, Liang-Nian He, Xinbin Ma
A series of Co3O4 catalysts with unique oxygen vacancy-hydroxyl FLPs were developed. The FLPs breaks the trade-off between CO2 adsorption and dissociation via forming a metastable d-HCO3 species, enabling the efficient synthesis of cyclic carbonates.
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From lab-scale performance to field barriers: electrocatalytic nitrate treatment for sustainable water remediation

2 novembre, 2025 - 18:05

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04166J, Tutorial ReviewZhenlin Mo, Wei Guo, Laiji Xu, Yiwen Chen, Shaoqi Zhou, Baojun Liu
A green circular economy system for converting industrial wastewater (nitrates) into agricultural resources (ammonia, energy).
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