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Machine learning-driven design of single-atom catalysts for carbon dioxide valorization to high-value chemicals: a review of photocatalysis, electrocatalysis, and thermocatalysis

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, 27,4898-4925
DOI: 10.1039/D5GC00739A, Tutorial ReviewXiangyu Wen, Xiao Geng, Guandong Su, Yizheng Li, Qidong Li, Yuxuan Yi, Lifen Liu
The research about photocatalytic, electrocatalytic, and thermocatalytic CO2 reduction, with single-atom catalysts (SACs).
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Biochemicals to enable biorefining: a case study of polyphenol extraction from bio-oil for utilization as a biodiesel antioxidant

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, 27,5027-5039
DOI: 10.1039/D5GC00184F, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaopeng Shi, Haotong Lin, Qi Ouyang, Guanqun Luo, Xianghong Lu, Jianbing Ji, Kaige Wang
This study developed a simple method to produce phenolic compounds from bio-oil, demonstrating their potential as sustainable biodiesel antioxidants with performance comparable to that of commercial products.
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A lactic acid dioxolane as a bio-based solvent for lithium-ion batteries: physicochemical and electrochemical investigations of lithium imide-based electrolytes

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, 27,5040-5050
DOI: 10.1039/D4GC05476H, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Massimo Melchiorre, Khai Shin Teoh, Juan Luis Gómez Urbano, Francesco Ruffo, Andrea Balducci
This work is the first report of a suitable formulation and application in lithium-ion battery full-cells of an electrolyte incorporating the novel bio-based solvent 5-methyl-1,3-dioxolane-4-one (LA-H,H) with imide-based salts.
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Organic carbonates as green media from laboratory syntheses to industrial applications

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC00536A, Critical ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Giacomo Trapasso, Fabio Aricò
The research for greener solvents is of paramount importance when aiming to a sustainable process. In order to be able to replace traditional hazardous media, green solvents must display negligible...
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Rationally design a cost-efficient and eco-friendly fluorinated ether for high-energy and long-lived Li-metal batteries

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC00474H, Papernan li, xue han, xinke cui, longji xu, chenxi liu, Qiao Han, Kai Xi, Zheng-Long Xu, Xiaobing Dai, Chong Mao, Lewen Yang, Weijiang Xue
Localized high-concentration electrolytes (LHCEs) are prevalent in high-voltage Li-metal batteries featuring their high specific energy and long cycle life. However, the most used component 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) for LHCEs is...
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Green chemistry perspectives on click chemistry approaches for cellulose functionalization: a critical review

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01227A, Critical ReviewBowen Li, Chaoqun Xu, Xinyi Zhu, Juan Yu, Xiaofang Zhang, Yimin Fan
Cellulose, Earth's most abundant renewable polymer, presents significant opportunities for sustainable materials development due to its inherent biodegradability, biocompatibility, and renewability. However, the efficient and environmentally benign functionalization of cellulose...
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Design of environmentally degradable polyethylene-like polyesters and eco-friendly recycling via commercial enzymes

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D4GC06604A, PaperHanxu Zhu, Han Hu, Xingyu Ouyang, Xiaokun Hong, Qingyang Luan, Jia-Yi Li, Jinggang Wang, Dongqing Wei, Jin Zhu
Polyethylene-like (PE-like) polyester represents a potential alternative to the most widely manufactured polyethylene materials, but has limited degradation rates and an environmentally unfriendly chemical recycling pathway. However, the green enzymatic...
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Green innovations in C–H bond functionalisation: exploring homogeneous recyclable catalytic systems

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00278H, Tutorial ReviewDewal S. Deshmukh, Sanjay Singh, Kirtikumar C. Badgujar, Vivek T. Humne, Gajanan V. Korpe, Bhalchandra M. Bhanage
This review focuses on homogeneous recyclable catalytic systems for direct C–H bond functionalization in organic synthesis, eliminating pre-functionalization. It explores recyclable catalysts with various metals and metal-free approaches.
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Metabolic Channelling in Rhodopseudomonas palustris for Hydroxyalkanoate Polymers Diversification and Sustainability Assessment

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D4GC05663A, PaperPoonam Kumari, S. Venkata Mohan
The increasing demand for sustainable alternatives to petrochemical-based plastics necessitates efficient biopolymer production methods. This study isolates and explores Rhodopseudomonas palustris SVMIICT10 for biosynthesis of polyhydroxyalkanoates under the effect of...
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Green Reactions by Metallosilicate Catalysts

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC00086F, Tutorial ReviewHao Xu, Jie Tuo, Longkang Zhang, Yue ma, Ye Jun Guan, Peng Wu
Metallosilicates, represented by TS-1 titanosilicate, have brought revolutionary green upgrades in the production of bulk chemicals by fabricating efficient selective oxidation catalytic systems since 1980s. The restrictions derived from the...
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Rational design of efficient Pt3Cu/TiO2 icosahedra catalysts for bio-aviation fuel production under a mild condition

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01235J, PaperYichen Nie, Xingyong Li, Misbah Uddin, Na Liu, Senshen Yu, Phidsavard Keomeesay, Olajide-rasheed Olalekan, Shuaizhe Li, yubao chen, Xuebing Zhao, Longlong Ma, Zhifeng Zheng, Shijie Liu
Bio-aviation fuel is a promising alternative sustainable aviation fuel (SAF) to fossil-based jet fuels. In this study, we employed a hydrothermal method to synthesize a novel catalyst of Pt3Cu/TiO2 icosahedra...
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Carbonized polymer dots as electrolyte additives for suppressing Zn dendrite growth, corrosion, and the HER in Zn-ion batteries

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00702J, PaperXiao-Yan Shen, Guo-Duo Yang, Xin-Yao Huang, Yan-Fei Li, Zhuo Wang, Tong Wang, Ru-Yi Liu, Yi-Han Song, Ming-Xiao Deng, Hai-Zhu Sun
Low-cost, eco-friendly CPDs are designed and synthesized as electrolyte additives to effectively enhance the stability of aqueous ZIBs. This work offers significant advancement in the development of green and clean energy storage devices.
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Insights into the photoelectrocatalytic lignin oxidation to value-added products using a niobium-doped titanium dioxide photoanode

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC00038F, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniela F.S. Morais, Luiza M.G. Sena, Joana Margarida Ribeiro, Telmo da Silva Lopes, Paula Dias, Adélio Mendes, Carina Costa, Alirio E. Rodrigues, Susana R.S. Pereira, Paula Pinto, Rui Alfredo Boaventura, Carlos J. Tavares, Vítor J.P. Vilar, Francisca C. C. Moreira
Pulp and paper industry generates high quantities of black liquor (BL), a lignin-rich waste stream with the potential to be converted into value-added products, such as low-molecular-weight phenolic products (LMPPs)....
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Gas-constructed assembled materials: a sustainable way for value-added and transformation of gas

Chemical News - 9 maggio, 2025 - 20:46
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D4GC05893C, PerspectiveYulian Zhang, Qiang Yan
The conversion and utilization of greenhouse gases and other polluting gases in a green way represents a crucial strategy for developing C1 chemistry and mitigating the dual crises of energy...
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Influence of functional additives, fillers, and pigments on thermal and catalytic pyrolysis of polyethylene for waste plastic upcycling

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00688K, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Harish Radhakrishnan, Abdulrahman A. B. A. Mohammed, Isabel Coffman, Xianglan Bai
Pyrolysis offers an economical method to convert waste plastics into valuable chemicals and fuels. However, the effects of various additives and impurities in waste plastics on the pyrolytic conversion must be better understood.
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Towards ultra-stable aqueous zinc-ion batteries via electrochemical polymerization of phthalimido-anchored benzoquinone

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01391G, PaperDan Wang, Yu-Xuan Bai, Zi-Xiang Zhou, Wei Cao, Yang-Min Ma, Chao Wang
Phthalimido anchored benzoquinone is selected as monomer for electropolymerization to fabricate the cathode of aqueous ZIBs with ultralong cycling stability.
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Enhancing the electroreduction of N2 and/or O2 on MoS2 using a nanoparticulate intrinsically microporous polymer (PIM-1)

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00612K, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Caio V. S. Almeida, Lara K. Ribeiro, Lucia H. Mascaro, Mariolino Carta, Neil B. McKeown, Frank Marken
Binding nitrogen gas into a microporous polymer close to an electrode surface increases the electrochemical production of ammonia.
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Electrochemically driven silicon–carbon bond cleavage of silacyclobutanes: a transition metal-free approach

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01185J, PaperYuanmeng Li, Jianshu Yue, Yinghui Shao, Yanni Yue, Hongping Deng, Xiaoli Bu, Mengtao Ma, Fei Xue
A sustainable and efficient electrochemical protocol has been developed for the synthesis of silyl ethers and silanols from SCBs under mild, metal-free conditions.
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Photo-promoted production of a new monophenolic compound from larch lignin with polyoxometalates supported on g-C3N4 under ambient conditions

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00692A, PaperHe Wan, Yang Liu, Chunhui Yu, Kuiyuan Cao, Yongwei Han, Zhong Sun, Junyou Shi, Xixin Duan
Mild conditions and high selectivity are challenging to achieve during the oxidative depolymerization of lignin into phenolic compounds.
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tert-Butyl hydroperoxide-mediated rapid 30-second oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Chemical News - 9 maggio, 2025 - 20:46

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00480B, PaperJian Liu, Ximing Zhang
A novel Au/CeO2-catalyzed TBHP system achieves 95% FDCA selectivity at full 5-HMF conversion in 30 s (90 °C), driven by stabilized radicals and van der Waals-enhanced spatial proximity for efficient oxidative activation.
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