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Performances and structural evolution of a new critical raw materials-free catalyst, synthesized from spent lithium-ion batteries, for solar-driven CO₂ conversion

Chemical News - 2 August, 2025 - 21:36
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02583D, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Antonella Cornelio, Alessandra Zanoletti, Giusy Dativo, Roberto Fiorenza, Annalisa Zacco, Mohsin Muhyuddin, Carlo Santoro, Laura Eleonora Depero, Elza Bontempi
The development of next-generation catalysts is crucial for advancing sustainable CO₂ conversion technologies and addressing pressing environmental challenges. This work integrates green chemistry principles by combining CO₂ valorization, waste recovery,...
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Making Polymers with Low Carbon Content is a Sustainable Option

Chemical News - 2 August, 2025 - 21:36
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02706C, PerspectiveYanni Xia, Chengjian Zhang, Xinghong Zhang
To copy with the challenges of the general polymer materials that rely on petroleum and produce pollution, we advocate partial substitution of carbon elements in polymers with oxygen (or other...
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Research Progress on Photocatalytic Production of Hydrogen Peroxide over MOFs and COFs

Chemical News - 2 August, 2025 - 21:36
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02617B, Critical ReviewYang An, Tianyan Cai, Weiyi Jiang, Tao Lei, Huan Pang
Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have shown great potential in the photocatalytic synthesis of hydrogen peroxide (H2O2) which has been taken as an important green oxidant extensively...
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Leaching state prediction for battery black mass using online sensor data

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC00581G, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wei Song, Andrey Yasinskiy, Fabian Diaz, Tobias Kleinert, Bernd Friedrich
An innovative process monitoring strategy during battery black mass leaching, using correlation analysis, regression modeling, and mechanistic interpretation.
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Intramolecular nitrogen insertion of oxime ester to access aminated N-heterocycles

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02482J, CommunicationHan Wang, Jing Feng, Dan-Ni Liu, Mingming Yu, Ze-Feng Xu, Chuan-Ying Li
A strategy for intramolecular nitrogen insertion of ketoxime esters to access aminated N-heterocycles is developed. It shows broad functional group tolerance, enables quetiapine fumarate synthesis, highlighting practical utility.
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Trifluoromethanesulfinyl chloride: an effective trifluoromethyl radical source in the trifluoromethylimination of alkenes

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01651G, CommunicationJiayu Liang, Shuping Wang, Xingda Zhao, Weilong Lin
CF3SOCl as CF3 source to achieve catalyst-free, highly regioselective intermolecular trifluoromethylimination of alkenes towards β-trifluoromethylamines.
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Renewable energy-driven synthesis of bioactive quinolinones through photocatalytic and electrochemical activation

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02521D, CommunicationQingge Zhao, Mengyu Peng, Huimin Li, Longqiang Zhao, Xinyue Song, Peiyao Zhao, Shoucai Wang, Guangbin Jiang, Fanghua Ji
We developed a dual photocatalytic/electrochemical system enabling sustainable, mild, and oxidant-free synthesis of quinolin-2(1H)-ones with broad scope, directly accessing pharmaceutical derivatives.
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Complementary acid site mechanisms in hydrogen-free polyethylene upcycling: elucidating the distinct roles of Brønsted and Lewis sites in Ce-modified zeolites

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01799H, PaperTaeeun Kwon, Jonghyun Park, Ki Hyuk Kang, Dae Sung Jung, Wangyun Won, Insoo Ro
Hydrogen-free upcycling of polyolefins over zeolite catalysts yields up to 88.7% naphtha. A linear structure–function relationship reveals that Brønsted acid sites promote β-scission, while strong Lewis acid sites enhance hydride abstraction.
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Photoinduced 1,2-cis glycosidation with catalytic amounts of NIS: minimizing the requirements for donor activation and additive dependent anomeric stereocontrol

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01243K, PaperJianwu Lv, Yongshun Qiu, Yuanyuan Li, Tianlu Li, Richard R. Schmidt, Peng Peng
We describe a simple and practical protocol utilizing 8% NIS in MTBE for efficient 1,2-cis glycosidations.
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25th Anniversary Celebration of Green Chemistry

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8686-8690
DOI: 10.1039/D5GC90115D, EditorialMichael A. Rowan, Andrea Carolina Ojeda Porras
Reflecting on Green Chemistry's history and celebrating 25 years of the journal's founding principles and recent initiatives aimed at supporting the next generation of green research.
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The low-temperature selective oxidation of alcohols and a one-pot oxidative esterification using an IBS(III/V)/oxone catalysis

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8804-8810
DOI: 10.1039/D5GC01737H, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ryutaro Kondo, Muhammet Uyanik, Kazuaki Ishihara
A low-temperature IBS(III/V)/oxone catalysis enables selective oxidation of alcohols and one-pot oxidative esterification under mild, metal-free, and sustainable conditions.
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Catalyst-free urea synthesis via plasma-driven direct coupling of CO2 and N2 under ambient conditions

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8811-8817
DOI: 10.1039/D5GC02193F, CommunicationDingwei Gan, Jingwen Huang, Longfei Hong, Haoxuan Jiang, Xiaoran Wang, Rusen Zhou, Jing Sun, Renwu Zhou
This study presents a catalyst-free urea synthesis technology using a dual-plasma reactor to couple CO2 and N2 under ambient conditions, enabling efficient nitrogen–carbon synergy for sustainable fertilizer production and carbon neutrality.
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Closed-loop recycling of spent Li6.5La3Zr1.5Ta0.5O12: from selective lithium recovery to high-efficiency sintering-aid preparation

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8950-8958
DOI: 10.1039/D5GC02023A, PaperYufan Zheng, Kexin Wan, Yuancheng Chen, Chuang Ji, Hongxiang Kuai, Xunhui Xiong
Selective lithium extraction from spent Li6.5La3Zr1.5Ta0.5O12 and preparation of lithium residue as an efficient sintering aid.
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Light empowered aziridination of olefins under metal- and photocatalyst-free conditions

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8980-8987
DOI: 10.1039/D5GC02150B, PaperBin Sun, Qian Zhang, Jianjie Wang, Yan Xu, Jiayin Wang, Chun Lv, Xiaohui Zhuang, Caiyun Yu, Can Jin
Aziridines derived from biologically active compounds often exhibit distinct pharmacological properties, rendering them highly valuable in the field of pharmacology.
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A mesoporous TiO2/carbon dot heterojunction photocatalyst efficiently cleaves entire types of C–O bonds in lignin under visible light

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8883-8900
DOI: 10.1039/D5GC01918D, PaperSong Han, Yun Zhao, Mina Liang, Xiangxiong Zhai, Qi Zhang, Na Sun, Rong Ma, Guoling Li, Zhubing Xiao, Zhonghai Ni
The progress of photocatalytic biomass depolymerization under mild conditions for the production of high-value chemicals has great potential.
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Selective C–O bond cleavage enhances aromatics production from lignin-derived platform molecules with ethanol as a hydrogen donor

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8959-8971
DOI: 10.1039/D5GC02104A, PaperHao Zhang, Qisong Yi, Huawei Geng, Zhifeng Liu, Wenhao Luo, Zichun Wang, Yuanshuai Liu
This study presents an efficient catalytic strategy that integrates aqueous-phase reforming of ethanol with selective hydrodeoxygenation of phenol to benzene.
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Dual functionalization of mesoporous organosilicon nanoflowers enhances heterogeneous chemoenzymatic conversion of alkynes toward enantiopure alcohols

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8858-8866
DOI: 10.1039/D5GC02373D, PaperChen Huang, Qian Zhang, Xiaoyang Yue, Aidang Lu, Guanhua Liu, Ying He, Li Ma, Liya Zhou, Yunting Liu, Yanjun Jiang
Two heterogeneous dual-functionalized mesoporous organosilicon nanoflower based chemo- and biocatalysts have been fabricated individually for the chemoenzymatic synthesis of chiral alcohols from alkynes.
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Sustainable approaches in vat photopolymerization: advancements, limitations, and future opportunities

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8710-8754
DOI: 10.1039/D5GC02299A, Critical ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Mirko Maturi, Erica Locatelli, Alberto Sanz de Leon, Mauro Comes Franchini, Sergio Ignacio Molina
Green resins for vat photopolymerization are critically assessed, highlighting bio-based feedstocks, synthetic trade-offs, and a unified green metric for guiding future materials design.
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Two-dimensional materials for high-current-density seawater electrolysis

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,8755-8776
DOI: 10.1039/D5GC01687H, Tutorial ReviewLiyun Wei, Jiao Dai, Shutong Qin, Mingjie Wang, Ziyuan Zhu, Weilin Xu, Kaisi Liu, Jun Wan
This review explores how two-dimensional materials uniquely respond to industrial-level current densities in seawater electrolysis, offering in-depth insights into structure-driven stability, selectivity, and green hydrogen production efficiency.
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Atom-efficient aldol condensation via magnetically recyclable nanoreactors: sol–gel imprinting enables template-switchable triple selectivity

Chemical News - 2 August, 2025 - 21:36

Green Chem., 2025, 27,9198-9210
DOI: 10.1039/D5GC02933C, PaperYa Liu, Jinghai Yan, Yi Hao, Xuemeng Tian, Yue Wang, Xueyi Liu, Ruixia Gao
By synergizing molecular precision with scalable selectivity and covalent durability, this work establishes a programmable green catalysis paradigm via magnetic sol–gel surface imprinting nanoreactor.
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