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A “wave-riding” biocatalysis: all-enzyme system toward genuine-green and flexible manufacture of machine-washable dyed wool fabrics
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01614B, PaperXinrui Zhang, Jun Wang, Man Zhou, Yuanyuan Yu, Ping Wang, Qiang Wang
The well-known phenomenon of felt shrinkage that occurs during home laundry of wool textiles has long bothered consumers. Currently, to address this issue, factories have no choice but to employ...
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DOI: 10.1039/D5GC01614B, PaperXinrui Zhang, Jun Wang, Man Zhou, Yuanyuan Yu, Ping Wang, Qiang Wang
The well-known phenomenon of felt shrinkage that occurs during home laundry of wool textiles has long bothered consumers. Currently, to address this issue, factories have no choice but to employ...
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Electrochemical selective incorporation of SO2 to synthesize the fused-ring framework
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01138H, PaperZhi-Long Lei, Dan Tan, Jin-Tao Qin, Xiu-Jin Meng, Fei-Hu Cui, Hai-Tao Tang, Ying-Ming Pan
The direct incorporation of sulfur dioxide into organic molecules, resulting in sulfur dioxide-containing compounds, aligns with the principle of achieving a high atomic economy within the domain of organic synthesis....
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DOI: 10.1039/D5GC01138H, PaperZhi-Long Lei, Dan Tan, Jin-Tao Qin, Xiu-Jin Meng, Fei-Hu Cui, Hai-Tao Tang, Ying-Ming Pan
The direct incorporation of sulfur dioxide into organic molecules, resulting in sulfur dioxide-containing compounds, aligns with the principle of achieving a high atomic economy within the domain of organic synthesis....
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Closed-loop recycling of bio-based disulfide vitrimer via a solvent-, waste-free strategy
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01872B, Communication
Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Solène Guggari, Fiona Magliozzi, Samuel Malburet, Alain Graillot, Mathias Destarac, Marc Guerre
This work presents a solvent-free recycling method for epoxy-based vitrimers using cystamine as a reactant and depolymerizing agent. The process depolymerize the vitrimer network via disulfide exchange, enabling the recovery...
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DOI: 10.1039/D5GC01872B, Communication
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Solène Guggari, Fiona Magliozzi, Samuel Malburet, Alain Graillot, Mathias Destarac, Marc GuerreThis work presents a solvent-free recycling method for epoxy-based vitrimers using cystamine as a reactant and depolymerizing agent. The process depolymerize the vitrimer network via disulfide exchange, enabling the recovery...
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Multifunctional 3-Cyanopyridine Compounds: Synthesis Based on Tandem Reaction with 100% Atomic Economy and Their Applications
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01264C, PaperXi-Ying Cao, Zhong-Hao Li, Xiaohui Cao, Zong Li, Chu-Ming Pang, Zu-Qi Zhang, Zhaoyang Wang
Employing a tandem reaction with 100% atomic economy, a series of novel 3-cyanopyridine derivatives were synthesized from benzopyrannitriles and pyrrolidines under mild and metal-free conditions with the promotion of sodium...
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DOI: 10.1039/D5GC01264C, PaperXi-Ying Cao, Zhong-Hao Li, Xiaohui Cao, Zong Li, Chu-Ming Pang, Zu-Qi Zhang, Zhaoyang Wang
Employing a tandem reaction with 100% atomic economy, a series of novel 3-cyanopyridine derivatives were synthesized from benzopyrannitriles and pyrrolidines under mild and metal-free conditions with the promotion of sodium...
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Monomer recycling of virgin polycarbonate (PC), end-of-life PC and PC-ABS blends by Ni-catalyzed reductive depolymerization
DOI: 10.1039/D4GC06438K, CommunicationCarlos Marquez, Annelore Aerts, Dambarudhar Parida, Illian Glassee, Harisekhar Mitta, Lingfeng Li, Kevin M. Van Geem, Karolien Vanbroekhoven, Elias Feghali, Kathy Elst
The reductive depolymerization of polycarbonate using affordable, heterogeneous and non-noble Ni catalysts was achieved, efficiently breaking down PC back to its monomer, bisphenol-A, in high yields.
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Organocatalytic aqueous formulations: green organocatalytic hydrophobization of heterogeneous polysaccharide-based materials in water through “on-water” mechanisms
DOI: 10.1039/D4GC06342B, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Rana Alimohammadzadeh, Dylan Ferreira, Zine Eddine Hamdouche, Tanel Mõistlik, Armando CórdovaGreen chemistry and sustainable technology for the fabrication of hydrophobic heterogeneous polysaccharide-based materials.
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Electrosynthesis of nitriles from primary alcohols and ammonia on Ni catalysts
DOI: 10.1039/D5GC00572H, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yiying Xiao, Chia Wei Lim, Linfeng Gao, Ning YanElectrosynthesis of nitriles from primary alcohols and ammonia was achieved using a simple Ni catalyst, with the highest benzonitrile faradaic efficiency being 62.9% and yields of up to 61.1%.
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Electronic structure and interfacial microenvironment engineering over the Ni(OH)2 nanoarray for boosted electrocatalytic upcycling of polyethylene terephthalate
DOI: 10.1039/D5GC00788G, PaperXinci Hu, Wei Qiao, Yuxin Hu, Fengli Li, Yuting Yang, Zhihong Jiang, Yu Yu, Jingyun Fang, Ping Li
The Ni foam-supported Ni(OH)2 nanosheet array with surface engineering of adipic acid is engineered to remarkably promote PET-derived ethylene glycol oxidation reaction (EGOR) for value-added formate production.
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Tailoring the extraction process and properties of polysaccharides from the lichen Evernia prunastri using natural eutectic solvents following a biorefinery approach
DOI: 10.1039/D5GC01413A, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Julie Queffelec, Maria Dolores Torres Pérez, Herminia Domínguez, Giulia Ischia, Svitlana FilonenkoOverview of the lichen processing.
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Solvent-promoted Catalyst-free Aminolytic Degradation for Chemical Recycling of Single and Mixed Plastic Wastes
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01068C, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kai Cheng, Yu-I Hsu, Hiroshi Uyama
The large-scale production of commodity plastics with poor degradability presents significant environmental and human health challenges. Instead of relying on landfilling or mechanical recycling, chemical recycling of plastic waste provides...
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DOI: 10.1039/D5GC01068C, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kai Cheng, Yu-I Hsu, Hiroshi UyamaThe large-scale production of commodity plastics with poor degradability presents significant environmental and human health challenges. Instead of relying on landfilling or mechanical recycling, chemical recycling of plastic waste provides...
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Enabling Desaturation of Lactones by Reversible Catalytic Activity of 'Ene'-reductases
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01533B, PaperFengxi Li, Yihang Dai, Shenhan Xie, Xinjia Yu, Xinyan Shi, Zhengqiang Li, Chuang Du, Zhi Wang, Lei Wang
An engineered old yellow enzyme lactone dehydrogenase (OYE1LD), which can reversibly catalyze the formation of C=C bonds and facilitate the conversion of lactones and ketones into their α, β-unsaturated counterparts...
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DOI: 10.1039/D5GC01533B, PaperFengxi Li, Yihang Dai, Shenhan Xie, Xinjia Yu, Xinyan Shi, Zhengqiang Li, Chuang Du, Zhi Wang, Lei Wang
An engineered old yellow enzyme lactone dehydrogenase (OYE1LD), which can reversibly catalyze the formation of C=C bonds and facilitate the conversion of lactones and ketones into their α, β-unsaturated counterparts...
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A microbial factory for bio-indigo synthesis: demonstration of sustainable denim dying
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01293G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matteo Planchestainer, Lin Chen, Tsvetan kardashliev, Sven Panke, Martin Held
Biotechnological production using genetically engineered bacteria has the potential allow environmentally friendly manufacturing of indigo with no toxic intermediates or side products being associated with traditional chemical process. The shikimate...
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DOI: 10.1039/D5GC01293G, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matteo Planchestainer, Lin Chen, Tsvetan kardashliev, Sven Panke, Martin HeldBiotechnological production using genetically engineered bacteria has the potential allow environmentally friendly manufacturing of indigo with no toxic intermediates or side products being associated with traditional chemical process. The shikimate...
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Aqueous phase synthesis of benzyl ester over partially thiolated Au25 nanocluster catalysts: improving selectivity with hydrophobic carbon support
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01292A, PaperKosuke Sakamoto, Koki Chida, Shinya Masuda, Takeharu Yoshii, Hirotomo Nishihara, Tatsuya Tsukuda
The aqueous phase synthesis of esters via oxidative coupling of the alcohols catalyzed by carbon-supported gold catalysts is one of the environmentally benign approaches, but remains challenging. To understand the...
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DOI: 10.1039/D5GC01292A, PaperKosuke Sakamoto, Koki Chida, Shinya Masuda, Takeharu Yoshii, Hirotomo Nishihara, Tatsuya Tsukuda
The aqueous phase synthesis of esters via oxidative coupling of the alcohols catalyzed by carbon-supported gold catalysts is one of the environmentally benign approaches, but remains challenging. To understand the...
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Direct Nitrile Electrosynthesis from Amino Acids on Nickel Oxyhydroxide
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01194A, CommunicationXudong Liu, Zhe Chen, Tao Jiang, Wei Du, Can Lei, Xueting Cao, Shuangshuang Cha, Mengxin Qu, Xinchi Zhou, Ming Gong
The anodic oxidation of biomass coupled with cathodic hydrogen evolution reaction (HER) is one of the most promising methods to simultaneously achieve sustainable hydrogen production and value-added chemical synthesis. Amino...
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DOI: 10.1039/D5GC01194A, CommunicationXudong Liu, Zhe Chen, Tao Jiang, Wei Du, Can Lei, Xueting Cao, Shuangshuang Cha, Mengxin Qu, Xinchi Zhou, Ming Gong
The anodic oxidation of biomass coupled with cathodic hydrogen evolution reaction (HER) is one of the most promising methods to simultaneously achieve sustainable hydrogen production and value-added chemical synthesis. Amino...
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Carbon-dot-modified phloroglucinol-glutaraldehyde resin photocatalysts for hydrogen peroxide production
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01193K, PaperJiarong Wang, Ning Li, Weijie Ren, Jie Wu, Qing Chang, Jinlong Yang, Shengliang Hu, Haolan Xu
Quinoid acceptor units are extremely important to phenolic resin photocatalysts for tuning charge separation and conversion utilization under solar irradiation. However, constructing quinoid acceptor in polycondensation reaction still faces critical...
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DOI: 10.1039/D5GC01193K, PaperJiarong Wang, Ning Li, Weijie Ren, Jie Wu, Qing Chang, Jinlong Yang, Shengliang Hu, Haolan Xu
Quinoid acceptor units are extremely important to phenolic resin photocatalysts for tuning charge separation and conversion utilization under solar irradiation. However, constructing quinoid acceptor in polycondensation reaction still faces critical...
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Two-Step Continuous Flow Aerobic Oxidation of Cannabidiol to Cannabinoquinone Derivatives
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01304F, PaperManuel Zielke, Christof Aellig, Dominique M. Roberge, Christopher A. Hone, C. Oliver Kappe
A two-step continuous flow oxidation procedure is presented for the preparation of Etrinabdione, a cannabidiol quinone derivative. Etrinabdione is currently undergoing clinical trials for the treatment of peripheral artery disease....
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DOI: 10.1039/D5GC01304F, PaperManuel Zielke, Christof Aellig, Dominique M. Roberge, Christopher A. Hone, C. Oliver Kappe
A two-step continuous flow oxidation procedure is presented for the preparation of Etrinabdione, a cannabidiol quinone derivative. Etrinabdione is currently undergoing clinical trials for the treatment of peripheral artery disease....
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Facile and rapid access to hexafluoroisopropanol (HFIP)-group functionalized aniline and indole derivatives using hexafluoroacetone trihydrate in HFIP
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC00878F, PaperXindi Li, Yuhao Wu, Jinshan Li, Jialin Xie, Juanzu Liu, Zhenchang Wen, Zhengdong Zhao, Chunman Jia
A series of structurally diverse HFIP group functionalized aniline and indole derivatives has been prepared through a simple procedure using cheap and widely available hexafluoroacetone trihydrate in hexafluoroisopropanol (HFIP) at...
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DOI: 10.1039/D5GC00878F, PaperXindi Li, Yuhao Wu, Jinshan Li, Jialin Xie, Juanzu Liu, Zhenchang Wen, Zhengdong Zhao, Chunman Jia
A series of structurally diverse HFIP group functionalized aniline and indole derivatives has been prepared through a simple procedure using cheap and widely available hexafluoroacetone trihydrate in hexafluoroisopropanol (HFIP) at...
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Developments of CO Surrogates for Base Metal Catalyzed Carbonylation
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01579K, Tutorial ReviewWenjing Li, Shentong Xie, Renyi Shi
Transition metal catalyzed carbonylation which introduces CO into organic molecules presents one of the most important tools to synthesize carbonyl derivatives. Despite the considerable synthetic utility of carbonylation reactions, their...
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DOI: 10.1039/D5GC01579K, Tutorial ReviewWenjing Li, Shentong Xie, Renyi Shi
Transition metal catalyzed carbonylation which introduces CO into organic molecules presents one of the most important tools to synthesize carbonyl derivatives. Despite the considerable synthetic utility of carbonylation reactions, their...
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Developing and improving enzyme-driven technologies to synthesise emerging prebiotics
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01723H, Tutorial Review Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Noelia Losada-Garcia, Milica Carević, Marija Ćorović, Ana Milivojević, Nikola M. Nikacevic, Cesar Mateo, Dejan Bezbradica, Jose M. Palomo
Emerging prebiotics, mainly oligosaccharides and phenolic compounds, are gaining increasing attention in the scientific community due to their health benefits and broad industrial potential. Prebiotics are widely used in foods,...
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DOI: 10.1039/D5GC01723H, Tutorial Review
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Noelia Losada-Garcia, Milica Carević, Marija Ćorović, Ana Milivojević, Nikola M. Nikacevic, Cesar Mateo, Dejan Bezbradica, Jose M. PalomoEmerging prebiotics, mainly oligosaccharides and phenolic compounds, are gaining increasing attention in the scientific community due to their health benefits and broad industrial potential. Prebiotics are widely used in foods,...
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N-Coordinated PdRh Synergy for High-Selective Ethylene Glycol Oxidation and Efficient Hydrogen Evolution
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC00784D, PaperHai-Yan Guo, Jinwei Kang, Yun-Yan Du, Lu Zhang, Jiu-Ju Feng, Ai-Jun Wang
The electrocatalytic oxidation of ethylene glycol as an anodic reaction (EGOR) offers a promising approach for producing both high-value chemical and hydrogen. However, achieving high selectivity for desired products while...
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DOI: 10.1039/D5GC00784D, PaperHai-Yan Guo, Jinwei Kang, Yun-Yan Du, Lu Zhang, Jiu-Ju Feng, Ai-Jun Wang
The electrocatalytic oxidation of ethylene glycol as an anodic reaction (EGOR) offers a promising approach for producing both high-value chemical and hydrogen. However, achieving high selectivity for desired products while...
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