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Unveiling the Five-Membered Ring Structures in “Soft” Coke Deposits on Fe-Ni Catalysts: Formation Mechanisms and Implications for Biomass Catalytic Reforming
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02932E, PaperWenkai Lang, Jin Deng, Xin Liu, Zaiyu Yang, Ruxia Zhang, Honghong Liu, Keyuan Sun, Shenfu Yuan
Coke deposits on catalysts during the reforming of biomass pyrolysis volatiles are usually the primary cause of catalyst deactivation and a major challenge for catalyst design. Unlike simple graphite carbon...
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DOI: 10.1039/D5GC02932E, PaperWenkai Lang, Jin Deng, Xin Liu, Zaiyu Yang, Ruxia Zhang, Honghong Liu, Keyuan Sun, Shenfu Yuan
Coke deposits on catalysts during the reforming of biomass pyrolysis volatiles are usually the primary cause of catalyst deactivation and a major challenge for catalyst design. Unlike simple graphite carbon...
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Controlling edge active-sites by vulcanizing bimetallic hydroxide for boosting oxygen evolution reaction
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02745D, PaperChengyu Fu, Min Zhang, Long Zhao, Yang Zhao, Li Shi, Yakun Tian, Yixing Luo, Qingsheng Wu, Yong Qing Fu, Ming Wen
Sulfur-laden wastewater can be served as a valuable resource to synthesize transition metal sulfides (TMSs) electrocatalysts to address the sluggish kinetics of oxygen evolution reaction (OER) in water splitting, which...
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DOI: 10.1039/D5GC02745D, PaperChengyu Fu, Min Zhang, Long Zhao, Yang Zhao, Li Shi, Yakun Tian, Yixing Luo, Qingsheng Wu, Yong Qing Fu, Ming Wen
Sulfur-laden wastewater can be served as a valuable resource to synthesize transition metal sulfides (TMSs) electrocatalysts to address the sluggish kinetics of oxygen evolution reaction (OER) in water splitting, which...
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Advancing perovskite solar cells with biomass-derived solvents: a pathway to sustainability
DOI: 10.1039/D5GC02249E, PaperJongil Bae, Jeongbeom Cha, Min Kim, Jeehoon Han
A viable roadmap for achieving high-performance, cost-competitive, and environmentally sustainable perovskite photovoltaics from a laboratory scale to a global scale, combined with the module lifetime of GVL/EA-based perovskite solar technology.
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A “wave-riding” biocatalysis: an all-enzyme system for genuinely green and flexible manufacture of machine-washable dyed wool fabrics
DOI: 10.1039/D5GC01614B, PaperXinrui Zhang, Jun Wang, Man Zhou, Yuanyuan Yu, Ping Wang, Qiang Wang
An all-enzyme strategy based on a “wave-riding” enzymatic mechanism was developed to achieve genuinely green manufacture of machine-washable dyed wool fabrics.
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Electrochemical ring-opening oxidation of aryl thianthrenium salts
DOI: 10.1039/D5GC02103K, PaperYong Yuan, Chunyan Bai, Yuyan Tao, Ya-Nan Zhang, Xiazhen Bao, Dongsheng Ji, Liwei Wang, Xiaotian Qi, Congde Huo
An interesting electrochemical ring-opening oxidation of aryl thianthrenium salts is accomplished without the need for chemical oxidizing reagents.
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Effective and Scalable Mechanochemical Synthesis of Platinum(II) Heteroleptic Anticancer Complexes
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02781K, PaperFatin Rashid, Christopher Gordon, Jennette Sakoff, Jayne Gilbert, Felipe García, Janice R Aldrich-Wright
With global cancer cases and their associated costs steadily increasing, there is an imperative for sustained research efforts to improve health outcomes and mitigate its socio-economic impact. Several treatments have...
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DOI: 10.1039/D5GC02781K, PaperFatin Rashid, Christopher Gordon, Jennette Sakoff, Jayne Gilbert, Felipe García, Janice R Aldrich-Wright
With global cancer cases and their associated costs steadily increasing, there is an imperative for sustained research efforts to improve health outcomes and mitigate its socio-economic impact. Several treatments have...
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Utilisation of Reactive Ionic Liquids for Energy Storage and Regulation of the Power Grid
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02519B, Perspective
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Merlin Kleoff, Franziska Klaucke, Patrick Voßnacker, Rainer Weber, Karsten Neuhoff, Sebastian Riedel
Chlorine is an essential feedstock for polymers and pharmaceuticals, with annual production exceeding 100 Mt. Nearly all Cl₂ is obtained by chlor-alkali electrolysis, which consumes about 2.58 MWh of electricity per...
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DOI: 10.1039/D5GC02519B, Perspective
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Merlin Kleoff, Franziska Klaucke, Patrick Voßnacker, Rainer Weber, Karsten Neuhoff, Sebastian RiedelChlorine is an essential feedstock for polymers and pharmaceuticals, with annual production exceeding 100 Mt. Nearly all Cl₂ is obtained by chlor-alkali electrolysis, which consumes about 2.58 MWh of electricity per...
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N,Se co-doped strategy to boost the K+ storage performance of metal organic framework-derived 3D amorphous carbon
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01554E, PaperYuyu Wang, Liangqin Cai, Shuo Yuan, Lin Feng, Zhen Guo, Shihua Dong
In view of the cost-effective, tunable interlayer spacing, and high electrical conductivity, carbonaceous materials are regarded as the most promising anodes for potassium-ion energy storage devices. Whereas, the poor diffusion...
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DOI: 10.1039/D5GC01554E, PaperYuyu Wang, Liangqin Cai, Shuo Yuan, Lin Feng, Zhen Guo, Shihua Dong
In view of the cost-effective, tunable interlayer spacing, and high electrical conductivity, carbonaceous materials are regarded as the most promising anodes for potassium-ion energy storage devices. Whereas, the poor diffusion...
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Synthesis and Characterization of 3-Hydroxybutyrate and 3-Hydroxy-9-octadecenoate Copolymer from Engineered Halomonas
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02422F, PaperXinyu Chen, Jiangnan Chen, Yan Xu, Qiong Wu, Fuqing Wu, George Guo-Qiang Chen
Polyhydroxyalkanoate (PHA) is a family of biodegradable polyesters accumulated by various microorganisms. Halophilic microorganism Halomonas bluephagenesis has been developed as a production platform strain for various PHA, chemicals and proteins...
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DOI: 10.1039/D5GC02422F, PaperXinyu Chen, Jiangnan Chen, Yan Xu, Qiong Wu, Fuqing Wu, George Guo-Qiang Chen
Polyhydroxyalkanoate (PHA) is a family of biodegradable polyesters accumulated by various microorganisms. Halophilic microorganism Halomonas bluephagenesis has been developed as a production platform strain for various PHA, chemicals and proteins...
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Polyphenolic Nanomaterials Ameliorated Salmonellosis Therapy via barrier restoration and microbiota regulation
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01363A, PaperTianyou Wang, Jinhong Dong, Bo Liang, Jianhua Zhang, Weijie Liu, Hengjie Zhang, Lei Yang, Yiwen Li, Xianchun Chen, Zhipeng Gu
Bacterial-induced salmonellosis poses a significant threat to patient health, yet conventional oral antibiotics, while effective in eliminating pathogens, can compromise intestinal barrier integrity and disturb gut microbial balance. In response,...
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DOI: 10.1039/D5GC01363A, PaperTianyou Wang, Jinhong Dong, Bo Liang, Jianhua Zhang, Weijie Liu, Hengjie Zhang, Lei Yang, Yiwen Li, Xianchun Chen, Zhipeng Gu
Bacterial-induced salmonellosis poses a significant threat to patient health, yet conventional oral antibiotics, while effective in eliminating pathogens, can compromise intestinal barrier integrity and disturb gut microbial balance. In response,...
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One-pot, in situ reductive catalytic approach for biomass furfural-based secondary amines at ambient conditions
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02500A, PaperPalanivel Subha, Qizhi Luo, Hu Li, Putla Sudarsanam
Biomass-based secondary amines are the versatile structural scaffolds of various drug molecules. This study reported a highly practical catalytic process for the room-temperature synthesis of renewable secondary amines from furfural...
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DOI: 10.1039/D5GC02500A, PaperPalanivel Subha, Qizhi Luo, Hu Li, Putla Sudarsanam
Biomass-based secondary amines are the versatile structural scaffolds of various drug molecules. This study reported a highly practical catalytic process for the room-temperature synthesis of renewable secondary amines from furfural...
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Engineered Pseudomonas putida: a Versatile Chassis for Lignin Valorization
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02312B, Critical ReviewHong-Wei Zhu, Chen Wang, Hai-Yuan Jia, Zhi-Hua Liu, Bing-Zhi Li
Lignin, a renewable aromatic polymer abundant in plant cell walls, represents a promising feedstock for producing high-value products. Lignin valorization offers a sustainable alternative to fossil-derived aromatics, playing a pivotal...
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DOI: 10.1039/D5GC02312B, Critical ReviewHong-Wei Zhu, Chen Wang, Hai-Yuan Jia, Zhi-Hua Liu, Bing-Zhi Li
Lignin, a renewable aromatic polymer abundant in plant cell walls, represents a promising feedstock for producing high-value products. Lignin valorization offers a sustainable alternative to fossil-derived aromatics, playing a pivotal...
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Application and mechanism of various modified nano zero-valent iron in wastewater treatment: A critical review
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02077H, Critical ReviewWei Teng, Kang Yang, Junhui Chen, Hongji Li, Junwei Han
The rising productivity and continuous discharge of inorganic/organic wastewater pose significant threats to human health and environmental safety, making contamination control an urgent priority. Nano zero-valent iron (nZVI) demonstrates exceptional...
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DOI: 10.1039/D5GC02077H, Critical ReviewWei Teng, Kang Yang, Junhui Chen, Hongji Li, Junwei Han
The rising productivity and continuous discharge of inorganic/organic wastewater pose significant threats to human health and environmental safety, making contamination control an urgent priority. Nano zero-valent iron (nZVI) demonstrates exceptional...
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Transforming orange by-products into high-value neuroprotective products: environmental and economic assessment of advanced green extraction methods
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02153G, Paper Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Brenda Lee Simas Porto, Berenice Acevedo-García, Ayla Elmi Kashtiban, Tulio Miranda Sepulveda, Miguel Herrero, Alejandro Cifuentes, Jose A. Mendiola, Elena Ibáñez
This study explores the valorization of orange by-products for the production of neuroprotective fractions using three extraction methods: maceration, Gas Expanded Liquid (GXL) extraction, and Pressurized Liquid Extraction (PLE). The...
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DOI: 10.1039/D5GC02153G, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Brenda Lee Simas Porto, Berenice Acevedo-García, Ayla Elmi Kashtiban, Tulio Miranda Sepulveda, Miguel Herrero, Alejandro Cifuentes, Jose A. Mendiola, Elena IbáñezThis study explores the valorization of orange by-products for the production of neuroprotective fractions using three extraction methods: maceration, Gas Expanded Liquid (GXL) extraction, and Pressurized Liquid Extraction (PLE). The...
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Closed-loop electro-upcycling of PET waste into formate and hydrogen via self-supported NiCo2O4 spinel arrays
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01993A, PaperMingkun Jiang, Yang Yang, Yujie Wang, Yajie Wang, Marina Ratova, Dan Wu
The global accumulation of polyethylene terephthalate (PET) waste poses a severe environmental crisis and leads to severe underutilization of embedded carbon resources. In this work, a self-supported spinel NiCo2O4 electrocatalyst...
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DOI: 10.1039/D5GC01993A, PaperMingkun Jiang, Yang Yang, Yujie Wang, Yajie Wang, Marina Ratova, Dan Wu
The global accumulation of polyethylene terephthalate (PET) waste poses a severe environmental crisis and leads to severe underutilization of embedded carbon resources. In this work, a self-supported spinel NiCo2O4 electrocatalyst...
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Life-cycle Environmental Impacts of Typical plasticizers for Plastics and the Sustainable Transformation Potential
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01960E, PaperYijun Li, Kai Zhao, Chi Wang, hang fu, Shanying Hu
Plasticizers are among the most used additives in the plastic industry, widely applied to improve the flexibility and processability of plastics. Despite the complex ecological and health risks associated with...
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DOI: 10.1039/D5GC01960E, PaperYijun Li, Kai Zhao, Chi Wang, hang fu, Shanying Hu
Plasticizers are among the most used additives in the plastic industry, widely applied to improve the flexibility and processability of plastics. Despite the complex ecological and health risks associated with...
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Quenching-triggered amorphous/crystalline-heterostructure with tensile strain achieves efficient alkaline HER kinetics by operating the unique Co1–P–Co2 electrocatalytic mechanism
DOI: 10.1039/D5GC02044A, PaperYunmei Du, Jinghan Xu, Shan Lu, Zhenyu Xiao, Yanru Liu, Kang Liu, Lei Wang
The CoOx/CoP-L nanosheets with 2.65% tensile strain were constructed by the 'phosphorization-quenching' treatment. In situ Raman combined with DFT reveal that heterostructure creates the unique Co1–P–Co2 electrocatalytic pathway for alkaline HER.
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Performances and structural evolution of a new critical raw materials-free catalyst, synthesized from spent lithium-ion batteries, for solar-driven CO₂ conversion
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02583D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Antonella Cornelio, Alessandra Zanoletti, Giusy Dativo, Roberto Fiorenza, Annalisa Zacco, Mohsin Muhyuddin, Carlo Santoro, Laura Eleonora Depero, Elza Bontempi
The development of next-generation catalysts is crucial for advancing sustainable CO₂ conversion technologies and addressing pressing environmental challenges. This work integrates green chemistry principles by combining CO₂ valorization, waste recovery,...
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DOI: 10.1039/D5GC02583D, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Antonella Cornelio, Alessandra Zanoletti, Giusy Dativo, Roberto Fiorenza, Annalisa Zacco, Mohsin Muhyuddin, Carlo Santoro, Laura Eleonora Depero, Elza BontempiThe development of next-generation catalysts is crucial for advancing sustainable CO₂ conversion technologies and addressing pressing environmental challenges. This work integrates green chemistry principles by combining CO₂ valorization, waste recovery,...
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Halide-ion induced reconstruction of Cu-based catalysts to form stable Cu0/Cu+ sites enabling efficient electroreduction of CO2 to C2+ products
DOI: 10.1039/D5GC03114A, PaperYahui Jiang, Haichuan He, Dan Xia, Hongwei Zhang, Shirui Tan, Li Luo, Yifan Kong, Liu Deng, You-Nian Liu
In situ halide ions induce the reconstruction of Cu-based catalysts, forming stable Cu0/Cu+ sites to enable highly efficient CO2 electroreduction toward C2+ products.
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Visible-light-induced and EDA complex-driven multicomponent reaction: A strategy for the synthesis of α-CF3-β-phosphorodithioate tertiary alcohols
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01349F, PaperMengqing Wang, Ziren Chen, Fei Xue, Qianqian Tan, Bin Wang, Yonghong Zhang, Yu Xia, Shaofeng Wu, Weiwei Jin, Xuefeng Jiang, Chenjiang Liu
A green and efficient synthetic strategy has been developed for the construction of α-trifluoromethyl-β-phosphorodithioate tertiary alcohols from trifluoromethyl alkenes, O2, P4S10, and alcohols via a visible-light-promoted, electron donor-acceptor (EDA) complex-driven...
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DOI: 10.1039/D5GC01349F, PaperMengqing Wang, Ziren Chen, Fei Xue, Qianqian Tan, Bin Wang, Yonghong Zhang, Yu Xia, Shaofeng Wu, Weiwei Jin, Xuefeng Jiang, Chenjiang Liu
A green and efficient synthetic strategy has been developed for the construction of α-trifluoromethyl-β-phosphorodithioate tertiary alcohols from trifluoromethyl alkenes, O2, P4S10, and alcohols via a visible-light-promoted, electron donor-acceptor (EDA) complex-driven...
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